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I'd suggest starting here:

• Any two of your sound sources
• One filter
• One granular module
• Shades
• Quadrax
• Quad VCA
• Output module (your Roland pick is fine, but you could go with something more simple as well)
• Pamela's New Workout (8 clocks or LFOs... so handy!)
• The Strymon pedal interface module

That's 10 modules... that's a ton to learn out of the gates, but still very powerful. Then after a few months, you'll start to understand what you really need to add next (if anything at all). But Luigi's point is important: do your homework on how synthesis functions first. If you're brand-new to synths, I'd strongly suggest picking up one of the various semi-modular monosynths as a starting point (O-Coast, Mother 32, Neutron, Crave, etc. etc.). Great way to get your feet wet, and get used to patching... and they'll still be relevant once you go for an actual modular system.